Search results for "surface condition"
showing 3 items of 3 documents
Boosting the in situ encapsulation of proteins with MIL-100(Fe): the role of strong Lewis acid centers
2021
Encapsulation of biomolecules using Metal-Organic Frameworks (MOFs) to form stable biocomposites has been demonstrated a valuable strategy for their preservation and controlled release, which has been however restricted to specific electrostatic surface conditions. We present a general in situ strategy that promotes the spontaneous MOF growth onto a broad variety of proteins, for the first time, regardless of their surface nature. We demonstrate that MOFs based on cations exhibiting considerable inherent acidity such as MIL-100(Fe) enable biomolecule encapsulation, including alkaline proteins previously inaccesible by the welldeveloped in situ encapsulation with azolate-based MOFs. In parti…
Regionalizing rainfall at very high resolution over la Réunion island using a regional climate model.
2014
Abstract Regional climate models (RCMs) should be evaluated with respect to their ability to downscale large-scale climate information to the local scales, which are sometimes strongly modulated by surface conditions. This is the case for La Réunion (southwest Indian Ocean) because of its island context and its complex topography. Large-scale atmospheric configurations such as tropical cyclones (TCs) may have an amplifying effect on local rainfall patterns that only a very high-resolution RCM, forced by the large scales and resolving finescale processes, may simulate properly. This paper documents the capability of the Weather Research and Forecasting Model (WRF) RCM to regionalize rainfall…
Nodular cast iron fatigue lifetime in cyclic plane bending
2012
The fatigue behavior of a component is strongly dependent on the material and its surface condition. Therefore, the manner in which the surface is prepared during component manufacturing (surface roughness, residual stresses etc.) has a decisive role in dictating the initiation time for fatigue cracks. The fatigue behavior of the same material, a nodular cast iron, with three different surface conditions (fine ground, sand blast and as-cast) has been investigated under cyclic plane bending. The results show differences in fatigue strength, which are associated with the surface conditions. The characteristics of the surface layers of the different test specimens were examined by metallograph…